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Question: Answered & Verified by Expert
0.02 mole of CoNH35BrCl2 and 0.02 mole of CoNH35ClSO4 are present in 200 cc of a solution X. The number of moles of the precipitates Y and Z that are formed when the solution X is treated with excess silver nitrate and excess barium chloride are respectively
ChemistryCoordination CompoundsJEE Main
Options:
  • A 0.02, 0.02
  • B 0.01, 0.02
  • C 0.02, 0.04
  • D 0.04, 0.02
Solution:
1314 Upvotes Verified Answer
The correct answer is: 0.04, 0.02
[Co(NH3)5Br]Cl21 mole0.02 mole+2AgNO32 moles[Co(NH3)5Br](NO3)21 mole+2AgCl(ppt.)(Y)2 moles0.02×2=0.04 mole

[Co(NH3)5Cl]SO41 mole+BaCl20.02 moles[Co(NH3)5Cl]Cl21 mole+BaSO4(ppt.)(Z)0.02 moles

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