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2O3g3O2g

At 300 K, ozone is fifty percent dissociated. The standard free energy change at this temperature and 1 atm pressure is -......J mol-1. (Nearest integer)

[Given: ln 1.35=0.3 and R=8.3 J K-1 mol-1]

ChemistryThermodynamics (C)JEE MainJEE Main 2022 (24 Jun Shift 1)
Solution:
1593 Upvotes Verified Answer
The correct answer is: 747

2O3g3O2g

Initially 1 mole 0

1-0.5 32×0.5

0.5 mole 1.52=0.75 mole

Kp=PO23PO32=0.751.2530.51.252=353252

=0.630.42=0.2160.16=1.35

ΔG°=-RTlnKp

=-8.3×300ln1.35

=-8.3×300×0.3

=-747J/mole

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