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Question: Answered & Verified by Expert
5 L of an alkane requires 25 L of oxygen for its complete combustion. If all volumes are measured at constant temperature and pressure, the alkane is
ChemistryHydrocarbonsJEE MainJEE Main 2016 (09 Apr Online)
Options:
  • A Isobutane
  • B Ethane
  • C Butane
  • D Propane
Solution:
1918 Upvotes Verified Answer
The correct answer is: Propane
Combustion of Hydrocarbon,

CxHy+x+y4O2x CO2+y2H2O

 nv (P,T=Constant)

for 1 mole of CxHy=x+y4O2 required

for 5 L of CxHy=x+y4 5 L, O2 required

 ratio of alkane and O2 is 5/25

So, x+y45=25

    x+y4=5,

which is satisfied by C3H8.
 

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