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'a' and 'b' are van der Waals' constants for gases. Chlorine is more easily liquefied than ethane because
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a for $\mathrm{Cl}_2>$ a for $\mathrm{C}_2 \mathrm{H}_6$ but $b$ for $\mathrm{Cl}_2 < $ b for $\mathrm{C}_2 \mathrm{H}_6$
a for $\mathrm{Cl}_2>$ a for $\mathrm{C}_2 \mathrm{H}_6$ but $b$ for $\mathrm{Cl}_2 < $ b for $\mathrm{C}_2 \mathrm{H}_6$
ease of liquefaction $\propto \frac{a}{b}$ for ethane $a=5.49, b=0.0638$ for $\mathrm{Cl}_2 \mathrm{a}=6.49, \mathrm{~b}=0.0562$
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