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Question: Answered & Verified by Expert
'a' and 'b' are van der Waals' constants for gases. Chlorine is more easily liquefied than ethane because
ChemistryStates of MatterJEE MainJEE Main 2011
Options:
  • A
    a and $b$ for $\mathrm{Cl}_2 < \mathrm{a}$ and $\mathrm{b}$ for $\mathrm{C}_2 \mathrm{H}_6$
  • B
    a for $\mathrm{Cl}_2 < $ a for $\mathrm{C}_2 \mathrm{H}_6$ but b for $\mathrm{Cl}_2>$ b for $\mathrm{C}_2 \mathrm{H}_6$
  • C
    a for $\mathrm{Cl}_2>$ a for $\mathrm{C}_2 \mathrm{H}_6$ but $b$ for $\mathrm{Cl}_2 < $ b for $\mathrm{C}_2 \mathrm{H}_6$
  • D
    a and $b$ for $\mathrm{Cl}_2>a$ and $b$ for $\mathrm{C}_2 \mathrm{H}_6$
Solution:
1097 Upvotes Verified Answer
The correct answer is:
a for $\mathrm{Cl}_2>$ a for $\mathrm{C}_2 \mathrm{H}_6$ but $b$ for $\mathrm{Cl}_2 < $ b for $\mathrm{C}_2 \mathrm{H}_6$
ease of liquefaction $\propto \frac{a}{b}$ for ethane $a=5.49, b=0.0638$ for $\mathrm{Cl}_2 \mathrm{a}=6.49, \mathrm{~b}=0.0562$

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