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Question: Answered & Verified by Expert
A benzene derivative did not produce white precipitate with the ammonical silver nitrate solution but decolorised the cold dilute alkaline $\mathrm{KMnO}_4$ solution. The compound is
ChemistryHydrocarbonsTS EAMCETTS EAMCET 2020 (10 Sep Shift 2)
Options:
  • A $\mathrm{C}_8 \mathrm{H}_6$
  • B $\mathrm{C}_8 \mathrm{H}_{10}$
  • C $\mathrm{C}_8 \mathrm{H}_8$
  • D $\mathrm{C}_7 \mathrm{H}_8$
Solution:
2998 Upvotes Verified Answer
The correct answer is: $\mathrm{C}_8 \mathrm{H}_8$
$\mathrm{C}_8 \mathrm{H}_8$ is


It is a derivative of benzene and decolorised the cold alkaline $\mathrm{KMnO}_4$ solution.
The reaction occurs as follows :
$\mathrm{C}_8 \mathrm{H}_8+2 \mathrm{KMnO}_4 \longrightarrow \mathrm{KC}_8 \mathrm{H}_5 \mathrm{O}_2$ $+2 \mathrm{MnO}_2+\mathrm{KOH}+\mathrm{H}_2 \mathrm{O}$

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