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Question: Answered & Verified by Expert
A brown coloured mixture of two gases is obtained by the reduction of 6N nitric acid with metallic copper. This mixture on cooling condenses to a blue liquid which on freezing at -30oC gives a blue solid. The correct choice for blue liquid or solid is.
Chemistryp Block Elements (Group 15, 16, 17 & 18)JEE Main
Options:
  • A It is referred to as the anhydride of nitrous acid.
  • B It is an acidic oxide and hence dissolves in alkalies producing nitrites.
  • C It can also be prepared by the action of 50% HNO3 on arsenious oxide and then cooling to 250 K.
  • D All of these.
Solution:
2397 Upvotes Verified Answer
The correct answer is: All of these.
(i) It is an acidic oxide and anhydride of HNO 2
N2O3+H2O2HNO2
(ii) With alkali it forms nitrites
N2O3+2NaOH2NaNO2+H2O
(iii) It can also be prepared by the action of 50% HNO3 on arsenious oxide and then cooling to 250 K
All are correct here.

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