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Question: Answered & Verified by Expert
A certain reaction AB follows the given concentration (molarity)-time graph. Which of the following statement is true?
ChemistryChemical KineticsJEE Main
Options:
  • A The reaction is of second order with respect to A
  • B The rate for this reaction at 40 second will be approximately 3.5×103Ms1
  • C The rate for this reaction at 80 second will be 1.75×10-3M s1
  • D The [B] will be 0.25 M at 60 second
Solution:
2301 Upvotes Verified Answer
The correct answer is: The rate for this reaction at 40 second will be approximately 3.5×103Ms1
Time required for concentration to change from 0.4to 0.2is same as the time required for the concentration to change from 0.2to 0.1, it means t 1/2 is independent of initial concentration, i.e. it is a first order reaction.
And from the graph t 1/2 =20s
K= 0.693 20 s 1
Rate=k[A]
At 40second [A]=0.1
rate= 0.693 20
=3.46× 10 3 Ms 1
=3.5× 10 3 s 1

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