A colorless substance ‘A’ (C 6 H 7 N) is sparingly soluble in water and gives a water soluble compound ‘B’ on treating with mineral acid. On reacting with CHCl 3 and alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’. Reaction of ‘A’ with benzenesulfonyl chloride gives compound ‘D’ which is soluble in alkali. With NaNO 2 and HCl, ‘A’ forms compound ‘E’ which reacts with phenol in alkaline medium to give an orange dye ‘F’. Identify compounds ‘D’ to ‘F’.

Question

A colorless substance ‘A’ (C 6 H 7 N) is sparingly soluble in water and gives a water soluble compound ‘B’ on treating with mineral acid. On reacting with CHCl 3 and alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’. Reaction of ‘A’ with benzenesulfonyl chloride gives compound ‘D’ which is soluble in alkali. With NaNO 2 and HCl, ‘A’ forms compound ‘E’ which reacts with phenol in alkaline medium to give an orange dye ‘F’. Identify compounds ‘D’ to ‘F’., D = N-Phenyl Benzene Sulphonamide, E = Benzenediazonium chloride and F = Azobenzene, D = Benzenesulfonamide, E = Benzenediazonium chloride and F = p-Hydroxy azobenzene, D = N-Phenyl Benzene Sulphonamide, E = Benzenediazonium chloride and F = p-Hydroxy azobenzene, D = N-Phenyl Benzene Sulphonamide, E = Benzene chloride and F = p-Hydroxy azobenzene

MARKS App · Accepted Answer

Correct Option is : (C) D = N-Phenyl Benzene Sulphonamide, E = Benzenediazonium chloride and F = p-Hydroxy azobenzene

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