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Question: Answered & Verified by Expert
A complex compound in which the oxidation number of a metal is zero is
ChemistryCoordination CompoundsJEE Main
Options:
  • A $\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
  • B $\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
  • C $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$
  • D $\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
Solution:
1813 Upvotes Verified Answer
The correct answer is: $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$
CO is a neutral ligand, so the oxidation state of metal in metal carbonyls is always zero.
$$
\begin{array}{r}
{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]} \\
\mathrm{x}+(0 \times 4)=0 \\
\mathrm{x}=0
\end{array}
$$

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