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Question: Answered & Verified by Expert
A compound formed by element $\mathrm{X}$ and $\mathrm{Y}$ crystallises in a cube and the $\mathrm{X}$ atoms are at the corners of a cube and the $\mathrm{Y}$ atoms are at the face centres. The formula of the compound is:
ChemistrySolid StateNEETNEET 2004
Options:
  • A $\mathrm{XY}_3$
  • B $\mathrm{X}_3 \mathrm{Y}$
  • C XY
  • D $\mathrm{XY}_2$
Solution:
1248 Upvotes Verified Answer
The correct answer is: $\mathrm{XY}_3$
In a unit cell, $\mathrm{X}$ atoms at the corners
$$
=\frac{1}{8} \times 8=1
$$
$Y$ atoms at the face centres $=\frac{1}{2} \times 6=3$
Ratio of $\mathrm{X}$ and $\mathrm{Y}=1: 3$. Hence formula is $\mathrm{XY}_3$.

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