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Question: Answered & Verified by Expert
A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy ΔU of the gas in joules will be
ChemistryThermodynamics (C)NEET
Options:
  • A – 500 J
  • B – 505 J
  • C + 505 J
  • D 1136.25 J
Solution:
2323 Upvotes Verified Answer
The correct answer is: – 505 J
As q = 0 so using I law of Thermodynamics.
ΔU=-p.ΔV
=-2.5(4.5-2.5)=-5 lit atm
=-5×101.3=-506.5 Joule
=-505 J

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