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Question: Answered & Verified by Expert
A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy ΔU of the gas in joules will be
ChemistryThermodynamics (C)NEETNEET 2017
Options:
  • A 1136.25 J.
  • B -500 J.
  • C -505 J.
  • D +505 J.
Solution:
2557 Upvotes Verified Answer
The correct answer is: -505 J.

ΔU=q+w

For adiabatic process, q=0

      ΔU=w

=-PΔV

= -2.5 atm×4.5-2.5L

= -2.5×2 L-atm

= -5×101.3 J

=-506.5 J

-505 J

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