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A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of the reactant is ______ min. (Nearest integer)
ChemistryChemical KineticsJEE MainJEE Main 2023 (10 Apr Shift 1)
Solution:
1327 Upvotes Verified Answer
The correct answer is: 2

For parallel reaction

When adding the rate constants of the two reactions, we need to use the formula for combining rate constants of two reactions in parallel, which is:

k=k1+k2

where k1 and k2 are the rate constants of the individual reactions.

In this case, the half-lives of the two reactions are 12 min and 3 min, respectively. The rate constants of the two reactions can be calculated using the formula for half-life of a first-order reaction:

1t1/2=112+13=512

Net t1/2=125=2.4 min2 min

Hence time taken for 50% consumption of reactant will be close to 2 min.

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