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Question: Answered & Verified by Expert
A polymer contains 50 molecules with molecular mass 5000, 100 molecules with molecular mass 10,000 and 50 molecules with molecular mass 15,000. Calculate number average molecular mass?
ChemistrySome Basic Concepts of ChemistryTS EAMCETTS EAMCET 2019 (03 May Shift 1)
Options:
  • A 5,000
  • B 75,000
  • C 10,000
  • D 20,000
Solution:
2871 Upvotes Verified Answer
The correct answer is: 10,000
$\because$ Number average molecular mass $(M n)$
$$
=\frac{N_2 M_2+N_2 M_2+N_3 M_3}{N_2+N_2+N_3}
$$
where, $N_2, N_2$ and $N_3$ are number of molecules and $M_2, M_2$ and $M_3$ are respectively their molecular masses.
Given,
$$
\begin{aligned}
& N_2=50 \text { and } M_2=5000 \\
& N_2=100 \text { and } M_2=10,000 \\
& N_3=50 \text { and } M_3=15,000
\end{aligned}
$$
Thus,

$$
\begin{aligned}
M \bar{n} & =\frac{N_1 M_1+N_2 M_2+N_3 M_3}{N_1+N_2+N_3} \\
& =\frac{(50 \times 5000)+(100 \times 10,000)+(50 \times 15000)}{50+100+50} \\
& =\frac{(25,0000)+(1,000,000)+(75,00,00)}{200} \\
M \bar{n} & =10,000
\end{aligned}
$$
Hence, option (3) is the correct answer.

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