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Question: Answered & Verified by Expert
A process has ΔH=200Jmol-1 and ΔS=40JK-1mol-1. Out of the values given below choose the minimum temperature above which the process will be spontaneous:
ChemistryThermodynamics (C)JEE MainJEE Main 2019 (10 Jan Shift 1)
Options:
  • A 20 K
  • B 5K
  • C 12K
  • D 4K
Solution:
2840 Upvotes Verified Answer
The correct answer is: 5K
G=H-TS ....... (Gibbs Helmholtz Equation)

For a reaction to be spontaneous, G<0

So, H-TS<0

H<TS

HS<T

i.e. Minimum temp. should be HS=20040=5K

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