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Question: Answered & Verified by Expert
A radioactive isotope, A undergoes simultaneous decay to different nuclei as :

Assuming that initially neither P nor Q was present, after how many hours, amount of Q will be just double to the amount of A remaining ?
ChemistryChemical KineticsJEE Main
Options:
  • A \( 6.0 \mathrm{~h} \)
  • B \( 7.0 \mathrm{~h} \)
  • C \( 8.0 \mathrm{~h} \)
  • D \( 5.0 \mathrm{~h} \)
Solution:
1146 Upvotes Verified Answer
The correct answer is: \( 6.0 \mathrm{~h} \)
t 1/2 (P)=2 t 1/2 (Q)
⇒ Q is formed at twice the rate of formation of P i.e., at any time t; [Q] = 2[P]
Rate constant for decay of A(k) = kP + kQ
k = ln 2 9 + ln 2 4 . 5
                      = ln 2 3 h -1
Let after t-hours, [Q] = 2 [A] and [P] = x%

Given, 2x = 2 (100 - 3x)
x = 2 5
t 3 ln 2 = ln( 1 0 0 1 0 0 - 3 x ) = ln 4
t = 6 . 0 h

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