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Question: Answered & Verified by Expert
A sample of gas is compressed by an average pressure of 0.50 atmosphere so as to decrease its volume from 400 cm3 to 200 cm 3 . During the process 8.00J of heat flows out to surroundings. The change in internal energy of the system is
ChemistryThermodynamics (C)JEE Main
Options:
  • A +2.13 J
  • B +10.13 J
  • C 2.13 J
  • D 10.13 J
Solution:
2593 Upvotes Verified Answer
The correct answer is: +2.13 J
Here, ΔV=200-400=-200 cm3
A we know 1Litre=1000  cm 3
ΔV=0.2Litre.
External Pressure P=0.50 then
Work done =-PΔV=+0.500.2
=+0.1atmLitre
and 1litre-atmosphere=101.3Joule
 W=+10.13 Joule
According to First law of thermodynamics
q=ΔE-W
then ΔE=q+W
Given q=-8.00 J
ΔE=8+10.13=2.13Joule

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