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Question: Answered & Verified by Expert
A solid has a structure in which 'W' atoms are located at the corners of a cubic lattice, oxygen atoms at the edge centre and $\mathrm{Na}$ atom at the body centre. The formula of the compound is
ChemistrySolid StateTS EAMCETTS EAMCET 2022 (20 Jul Shift 2)
Options:
  • A $\mathrm{NaWO}_2$
  • B $\mathrm{Na}_2 \mathrm{WO}_3$
  • C $\mathrm{NaWO}_3$
  • D $\mathrm{NaWO}_4$
Solution:
2039 Upvotes Verified Answer
The correct answer is: $\mathrm{NaWO}_3$


$\therefore$ Effective no. of atoms in one unit cell
$$
\begin{aligned}
& =8 \times \frac{1}{8}+12 \times \frac{1}{4}+1 \times 1 \\
& =1+3+1
\end{aligned}
$$
(W) $(\mathrm{O})(\mathrm{Na})$
The formula of the compound $=\mathrm{NaWO}_3$.

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