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A solution of $\mathrm{FeCl}_3$ in water acts as acidic due to
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Hydrolysis of $\mathrm{Fe}^{3+}$
$\mathrm{FeCl}_3+3 \mathrm{H}_2 \mathrm{O} \rightleftharpoons \mathrm{Fe}(\mathrm{OH})_3+3 \mathrm{HCl}$. Strong acid and weak base.
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