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Question: Answered & Verified by Expert
A variable, the opposite external potential (Eext) is applied to the cell Zn | Zn2+ 1MCu2+ 1 M| Cu, of potential 1.1 V. When Eext<1.1 V and Eext>1.1 V, respectively electrons flow from
ChemistryElectrochemistryJEE MainJEE Main 2015 (10 Apr Online)
Options:
  • A anode to cathode in both the cases.
  • B anode to cathode and cathode to anode.
  • C cathode to anode and anode to cathode.
  • D cathode to anode in both cases.
Solution:
2324 Upvotes Verified Answer
The correct answer is: anode to cathode and cathode to anode.
For a Daniel cell,

Ecell=0.34-(-0.76)=1.10 V.

When Eext<1.10 V, electrons flow from anode to cathode in the external circuit.

When Eext>1.10 V, electrons flow from cathode to anode in the external circuit (reverse reaction).

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