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Question: Answered & Verified by Expert
According to MO theory the bond orders for O22-, CO and NO+ respectively, are
ChemistryChemical Bonding and Molecular StructureJEE MainJEE Main 2023 (29 Jan Shift 2)
Options:
  • A 1,3 and 3
  • B 1,3 and 2
  • C 1,2 and 3
  • D 2,3 and 3
Solution:
1473 Upvotes Verified Answer
The correct answer is: 1,3 and 3

(i) Molecular orbital configuration of O22- is KK (σ2s)2 (σ*2s)2 𝜋(2px)2 𝜋(2py)2 (σ2pz)2 𝜋*(2px)2 𝜋*(2py)2

Bond order = 12 (Nb - Na) = 12 8 - 6 = 1

(ii) Molecular orbital configuration of CO is KK (σ2s)2 (σ*2s)2 𝜋(2px)2 𝜋(2py)2 (σ2pz)2 

Bond order = 12 (Nb - Na) = 12 8 - 2 = 3

(iii) Molecular orbital configuration of NO+ is KK (σ2s)2 (σ*2s)2 𝜋(2px)2 𝜋(2py)2 (σ2pz)2 

Bond order = 12 (Nb - Na) = 12 8 - 2 = 3

So, according to molecular orbital theory, the bond orders respectively are 1, 3 and 3.

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