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Question: Answered & Verified by Expert
Acetic anhydride is prepared in the laboratory by heating sodium acetate with
ChemistryCarboxylic Acid DerivativesJIPMERJIPMER 2012
Options:
  • A ethyl chloride
  • B acetyl chloride
  • C conc. $\mathrm{H}_2 \mathrm{SO}_4$
  • D zinc dust
Solution:
2100 Upvotes Verified Answer
The correct answer is: acetyl chloride
In laboratory, acetic anhydride is prepared by heating sodium acetate with acetyl chloride.
$\mathrm{CH}_3 \mathrm{COONa}+\underset{\text { acetyl chloride }}{\mathrm{CH}_3 \mathrm{COCl}} \xrightarrow[-\mathrm{NaCl}]{\Delta} \underset{\text { acetic anhydride }}{\mathrm{CH}_3 \mathrm{COOCOCH}_3}$

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