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Question: Answered & Verified by Expert
Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide gives a Prussian blue coloured colloidal species. It is:
ChemistryCoordination CompoundsJEE MainJEE Main 2021 (27 Aug Shift 1)
Options:
  • A HFeFe(CN)6
  • B K5FeFe(CN)62
  • C Fe4Fe(CN)63
  • D KFeFe(CN)6
Solution:
1941 Upvotes Verified Answer
The correct answer is: KFeFe(CN)6

If we add ferric chloride over potassium ferrocyanide, it forms a white precipitate that will become blue. The reaction is

FeCl3+K4Fe(CN)6KFeFe(CN)6+3KCl

Being small quantity of ferric chloride, not all potassium is displaced.

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