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Question: Answered & Verified by Expert
AgNO3aq was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductivity Λ versus the volume of AgNO3 is

ChemistryElectrochemistryJEE Main
Options:
  • A (P)
  • B (Q)
  • C (R)
  • D (S)
Solution:
1177 Upvotes Verified Answer
The correct answer is: (S)
AgNO3+KClaqAgCls+KNO3aq

Initially there is aq. KCl solution now as solution of AgNO3 is added, AgCls is formed. Hence conductivity of solution is almost compensated (or slightly increase) by the formation of KNO3 . After end point conductivity increases more rapidly because addition of excess AgNO3 solution.

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