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Although $\mathrm{CN}^{-}$ion and $\mathrm{N}_2$ molecule are isoelectronic, yet $\mathrm{N}_2$ molecule is chemically inert because of
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absence of bond polarity
absence of bond polarity
In nitrogen molecule, both the nitrogen atoms have same electronegativity. So it has zero polarity and hence less tendency to break away and form ions.
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