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Although Zirconium belongs to 4d and hafnium belongs to 5d transition series, they show similar physical and chemical properties because both
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have similar atomic radius
This is because the atomic radii of 4d and 5d transition elements are nearly same. This similarity in size is due to lanthanoid contraction. Because of this contraction the radius of becomes nearly equal to that of and as the properties of an element depends on its atomic radii they show similar properties.
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