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Question: Answered & Verified by Expert
Among $\mathrm{Al}_2 \mathrm{O}_3, \mathrm{SiO}_2, \mathrm{P}_2 \mathrm{O}_3$ and $\mathrm{SO}_2$ the correct order of acid strength is
ChemistryClassification of Elements and Periodicity in PropertiesJEE Main
Options:
  • A $\mathrm{Al}_2 \mathrm{O}_3 \lt \mathrm{SiO}_2 \lt \mathrm{SO}_2 \lt \mathrm{P}_2 \mathrm{O}_3$
  • B $\mathrm{SiO}_2 \lt \mathrm{SO}_2 \lt \mathrm{Al}_2 \mathrm{O}_3 \lt \mathrm{P}_2 \mathrm{O}_3$
  • C $\mathrm{SO}_2 \lt \mathrm{P}_2 \mathrm{O}_3 \lt \mathrm{SiO}_2 \lt \mathrm{Al}_2 \mathrm{O}_3$
  • D $\mathrm{Al}_2 \mathrm{O}_3 \lt \mathrm{SiO}_2 \lt \mathrm{P}_2 \mathrm{O}_3 \lt \mathrm{SO}_2$
Solution:
1127 Upvotes Verified Answer
The correct answer is: $\mathrm{Al}_2 \mathrm{O}_3 \lt \mathrm{SiO}_2 \lt \mathrm{P}_2 \mathrm{O}_3 \lt \mathrm{SO}_2$
With decrease in size from Al to S the basic nature of oxide decrease and acidic nature increases.
$\mathrm{Al}_2 \mathrm{O}_3 \lt \mathrm{SiO}_2 \lt \mathrm{P}_2 \mathrm{O}_3 \lt \mathrm{SO}_2$
$\mathrm{Al}_2 \mathrm{O}_3$ is amphoteric, $\mathrm{SiO}_2$ is slightly acidic whereas $\mathrm{P}_2 \mathrm{O}_3$ and $\mathrm{SO}_2$ are the anhydrides of acids
$\mathrm{H}_3 \mathrm{PO}_3 \text { and } \mathrm{H}_2 \mathrm{SO}_3 \text {. }$

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