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Question: Answered & Verified by Expert
Among $\mathrm{Me}_{3}\mathrm{N}, \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}$ and MeCN
(Me $=$ methyl group) the electronegativity of $\mathrm{N}$ is in the order
ChemistryClassification of Elements and Periodicity in PropertiesWBJEEWBJEE 2017
Options:
  • A $\mathrm{MeCN}>\mathrm{C}_{\mathrm{g}} \mathrm{H}_{\mathrm{s}} \mathrm{N}>\mathrm{Me}_{3} \mathrm{N}$
  • B $\mathrm{C}_{3} \mathrm{H}_{5} \mathrm{N}>\mathrm{Me}_{3} \mathrm{N}>\mathrm{MeCN}$
  • C $\mathrm{Me}_{3} \mathrm{N}>\mathrm{MeCN}>\mathrm{C}_{3} \mathrm{H}_{\mathrm{s}} \mathrm{N}$
  • D Electronegativity same in all
Solution:
1900 Upvotes Verified Answer
The correct answer is: $\mathrm{MeCN}>\mathrm{C}_{\mathrm{g}} \mathrm{H}_{\mathrm{s}} \mathrm{N}>\mathrm{Me}_{3} \mathrm{N}$
$\because$ In Me $_{3} \mathrm{N} \rightarrow \mathrm{N}$ is $s p^{3}$ -hybrid


and in $\mathrm{MeCN} \rightarrow \mathrm{N}$ is $s p$ -hybrid Also electronegativity of any element $\alpha \%$ $s$ -character in hybrid orbitals. Thus, order of electronegativity for nitrogen is
$$
\mathrm{MeCN}>\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N} < \mathrm{Me}_{3} \mathrm{N}
$$

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