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Question: Answered & Verified by Expert
Among the compounds
(i) $\mathrm{H}-\mathrm{C} \equiv \mathrm{C}-\mathrm{COOH}$
(ii) $\mathrm{CH}_2=\mathrm{CH}-\mathrm{COOH}$
(iii) $\mathrm{CH}_3-\mathrm{CH}_2 \mathrm{COOH}$ and
(iv) $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{OH}$
The correct order of acid strength is
ChemistryGeneral Organic ChemistryTS EAMCETTS EAMCET 2022 (20 Jul Shift 2)
Options:
  • A (i) > (ii) > (iii) > (iv)
  • B (iv) > (iii) > (ii) > (i)
  • C (ii) > (i) > (iv) > (iii)
  • D (iii) > (ii) > (i) > (iv)
Solution:
2469 Upvotes Verified Answer
The correct answer is: (i) > (ii) > (iii) > (iv)
Carboxylic acids are more acidic than alcohol. As the 's'-character in the $\mathrm{C}_{\mathrm{x}}$ increases, the acidity of carboxylic acid increases.

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