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Question: Answered & Verified by Expert
Among the following pairs of ions, the lower oxidation state in aqueous solution is more stable than the other, in
Chemistryd and f Block ElementsAIIMSAIIMS 2005
Options:
  • A $\mathrm{Tl}^{+}, \mathrm{Tl}^{3+}$
  • B $\mathrm{Cu}^{+}, \mathrm{Cu}^{2+}$
  • C $\mathrm{Cr}^{2+}, \mathrm{Cr}^{3+}$
  • D $\mathrm{V}^{2+}, \mathrm{VO}^{2+}$.
Solution:
1832 Upvotes Verified Answer
The correct answer is: $\mathrm{Tl}^{+}, \mathrm{Tl}^{3+}$
$\mathrm{Tl}^{+}$ions are more stable than $\mathrm{Tl}^{3+}$ and thus, $\mathrm{Tl}^{3+}$ ions change to $\mathrm{Tl}^{+}$ions thereby acting as oxidising agents.
$\mathrm{Tl}^{3+}$ compounds $+2 e^{-} \rightarrow \mathrm{Tl}^{+}$compounds
(less stable, oxidising agent) (more stable, reducing agent)

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