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Question: Answered & Verified by Expert
Among the following the incorrect statement about transition metals is
Chemistryd and f Block ElementsTS EAMCETTS EAMCET 2023 (14 May Shift 1)
Options:
  • A $\mathrm{Cr}$, Mo and $\mathrm{W}$ have high melting points
  • B With increase in number of unpaired electrons melting point increases
  • C $\mathrm{Mn}^{3+}$ is more stable than $\mathrm{Mn}^{2+}$
  • D They show variable oxidation states
Solution:
2307 Upvotes Verified Answer
The correct answer is: $\mathrm{Mn}^{3+}$ is more stable than $\mathrm{Mn}^{2+}$
$\mathrm{Mn}=[\mathrm{Ar}] 3 \mathrm{~d}^5 4 \mathrm{~s}^2$
$$
\mathrm{Mn}^{2+}=[\mathrm{Ar}] 3 \mathrm{~d}^5 \text { and } \mathrm{Mn}^{3+}=[\mathrm{Ar}] 3 \mathrm{~d}^4
$$

Thus, the half-filled configuration of $\mathrm{Mn}^{2+}$ leads to its greater stability.

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