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Question: Answered & Verified by Expert
Among the following the paramagnetic compound is
ChemistryChemical Bonding and Molecular StructureNEET
Options:
  • A O3
  • B N2O
  • C Na2O2
  • D KO2
Solution:
1444 Upvotes Verified Answer
The correct answer is: KO2
Na2O2 or O22-=σ1s2σ*1s2,σ2s2σ*2s2,σ2pZ2,π2pX2=π2pY2,π*2pX2=π*2pY2
Number of unpaired electrons = 0
N=NO number of unpaired electrons =0
O=OO-O=OO
Number of unpaired electrons =0
KO2 or O2-=σ1s2,σ*1s2σ2s2,σ*2s2,σ2pZ2,π2pX2=π2pY2,π*2pX2=π*2pY1
Number of unpaired electrons =1
So O2- is paramagnetic.

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