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Question: Answered & Verified by Expert
Among the following, which is the strongest Lewis acid?
ChemistryIonic EquilibriumNEET
Options:
  • A BF3
  • B BCl3
  • C BBr3
  • D BI3
Solution:
2004 Upvotes Verified Answer
The correct answer is: BI3
The strengths of boron halides as Lewis acids are in the order BI 3 > BBr 3 > BCl 3 > BF 3 . This order is the opposite of what is expected on steric grounds as well as from considerations of electronegatively. It can be explained in terms of boron-halogen-bonding.
Here, acidic nature 1extenobackbonding

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