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Among the statements , the incorrect ones are:
Octahedral complexes with strong field ligands have very high magnetic moments
When , the d-electron configuration of in an octahedral complex is
Wavelength of light absorbed by is lower than that of
If the for an octahedral complex of is , the for its tetrahedral complex with the same ligand will be .
Options:
Octahedral complexes with strong field ligands have very high magnetic moments
When , the d-electron configuration of in an octahedral complex is
Wavelength of light absorbed by is lower than that of
If the for an octahedral complex of is , the for its tetrahedral complex with the same ligand will be .
Solution:
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Verified Answer
The correct answer is:
and only

So if there are strong field ligands in complex, pairing of electrons will take place, due to which number of unpaired electrons decrease due to which magnetic moment decrease.
Splitting power of ethylenediamine (en) is greater than fluoride ligand therefore more energy absorbed by as compared to
So wave length of light absorbed by is lower than that of
Statement and are incorrect.
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