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Question: Answered & Verified by Expert
An alkyl bromide $(X)$ reacts with sodium in ether to form 4,5 -diethyl octane, the compound $X$ is
ChemistryHydrocarbonsKCETKCET 2013
Options:
  • A $\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}$
  • B $\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{Br}$
  • C $\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}$
  • D $\mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{2}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
Solution:
2572 Upvotes Verified Answer
The correct answer is: $\mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{2}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
Alkyl halides react with metallic Na in presence of dry ether to form symmetrical alkanes containing double the number of carbon atoms present in the alkyl halide.



This reaction is called Wurtz reaction.

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