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Question: Answered & Verified by Expert
An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation of HS from H2S is 1.0×10-7 and that of S2- from HS- ions is 1.2×10-13 then the concentration of S2- ions in aqueous solution is
ChemistryChemical EquilibriumNEET
Options:
  • A 5×10-19
  • B 5×10-8
  • C 3×10-20
  • D 6×10-21
Solution:
1954 Upvotes Verified Answer
The correct answer is: 3×10-20
H2S(aq)(0.1-x)=0.12H+(2x+0.20)0.2+S2-x,
Ka=Ka1=1.2×10-20
1.2×10-20=(0.2)2×[S2-]0.1
[S2-]=3×10-20 '

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