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Question: Answered & Verified by Expert
An electron is moving in Bohr's fourth orbit. Its de-Broglie wave length is $\lambda$. What is the circumference of the fourth orbit?
ChemistryStructure of AtomJIPMERJIPMER 2014
Options:
  • A $\frac{2}{\lambda}$
  • B $2 \lambda$
  • C $4 \lambda$
  • D $\frac{4}{\lambda}$
Solution:
2631 Upvotes Verified Answer
The correct answer is: $4 \lambda$
According to Bohr's concept, an electron always move in the orbit with angular momentum (mvr) equal to $n h / 2 \pi$.
$\therefore \quad m v r=\frac{n h}{2 \pi}$
or $r=\frac{n}{2 \pi} \cdot\left(\frac{h}{m v}\right)$
Or $r=\frac{n \lambda}{2 \pi}$
(from de-Broglie equation, $\lambda=\frac{h}{m v}$ )
For fourth orbit $(n=4)$,
$\begin{gathered}r=\frac{2 \lambda}{\pi} \\ \therefore \text { Circumference }=2 \pi r=2 \pi \times \frac{2 \lambda}{\pi}=4 \lambda\end{gathered}$

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