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Question: Answered & Verified by Expert
An elemental crystal has a density of $8570 \mathrm{~kg} / \mathrm{m}^{3}$. The packing efficiency is 0.68 . The closest distance of approach between neighbouring atom is $2.86 Ã…$. What is the mass of one atom approximately?
ChemistrySolid StateBITSATBITSAT 2014
Options:
  • A $93 \mathrm{amu}$
  • B $39 \mathrm{amu}$
  • C $63 \mathrm{amu}$
  • D $29 \mathrm{amu}$
Solution:
1457 Upvotes Verified Answer
The correct answer is: $93 \mathrm{amu}$
The packing efficiency $=0.68$, means the given lattice is $\mathrm{BCC}$. The closest distance of approach $=2 \mathrm{r}$

$$

\begin{array}{l}

2 r=2.86 A=a \sqrt{3} \\

\text { or a }=\frac{2 \times 2.86}{\sqrt{3}}=3.30 Ã…

\end{array}

$$

Let atomic weight of the element $=\mathrm{a}$

$$

\begin{aligned}

\therefore & \frac{2 \times 9}{36 \times 10^{23} \times(3.3)^{3} \times 10^{-24}}=8.57 \\

\mathrm{a} &=8.57 \times 3 \times(3.3)^{3} \times 0.1 \\

&=92.39 \simeq 93 \mathrm{amu}

\end{aligned}

$$

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