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Question: Answered & Verified by Expert
An ester \( \mathrm{A}\left(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{2}\right) \), on treatment with excess methyl magnesium chloride followed by acidification, gives an alcohol \( \mathrm{B} \) as the sole organic product. Alcohol \( \mathrm{B} \), on oxidation with \( \mathrm{NaOCl} \) followed by acidification, gives acetic acid. Ester A is:
ChemistryCarboxylic Acid DerivativesJEE Main
Options:
  • A
  • B
  • C
  • D
Solution:
1691 Upvotes Verified Answer
The correct answer is:

The given ester reacts with excess of Grignard reagent forms 2-propanol as a single alcohol product. 2-propanol on oxidation with NaOCl, gives acetic acid and chloroform(It is a haloform reaction). The reaction are shown below,

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