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Question: Answered & Verified by Expert
An excited hydrogen atom emits a photon of wavelength ' $\lambda$ ' in returning to ground state. The quantum number ' $n$ ' of the excited state is ( $\mathrm{R}=$ Rydberg's constant)
PhysicsDual Nature of MatterMHT CETMHT CET 2023 (13 May Shift 2)
Options:
  • A $\sqrt{\lambda \cdot R(\lambda R-1)}$
  • B $\sqrt{\frac{\lambda \mathrm{R}}{(\lambda \mathrm{R}-1)}}$
  • C $\sqrt{\frac{(\lambda \mathrm{R}-1)}{\lambda \mathrm{R}}}$
  • D $\sqrt{\frac{1}{\lambda \mathrm{R}(\lambda \mathrm{R}-1)}}$
Solution:
1290 Upvotes Verified Answer
The correct answer is: $\sqrt{\frac{\lambda \mathrm{R}}{(\lambda \mathrm{R}-1)}}$
Using Rydberg's formula
$\frac{1}{\lambda}=\mathrm{R}\left[\frac{1}{1^2}-\frac{1}{\mathrm{n}^2}\right] \quad \ldots(\because \mathrm{m}=1)$
$\therefore \quad \frac{\mathrm{n}^2-1}{\mathrm{n}^2}=\frac{1}{\lambda \mathrm{R}} \Rightarrow 1-\frac{1}{\mathrm{n}^2}=\frac{1}{\lambda \mathrm{R}} \Rightarrow \frac{\lambda \mathrm{R}-1}{\lambda \mathrm{R}}=\frac{1}{\mathrm{n}^2}$
$\therefore \quad \mathrm{n}=\sqrt{\frac{\lambda \mathrm{R}}{\lambda \mathrm{R}-1}}$

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