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Question: Answered & Verified by Expert
An open manometer attached to a flask containing ammonia gas have no difference in mercury level initially as shown in diagram. After sparking into the flask, ammonia is partially dissociated as 2 NH 3 g N 2 g + 3 H 2 g . Now it have difference of 18cm in mercury level in two columns, what is partial pressure of H 2 g at equilibrium ?

ChemistryStates of MatterJEE Main
Options:
  • A 9cm of Hg
  • B 18 cm of Hg
  • C 27cm of Hg
  • D None of these
Solution:
1310 Upvotes Verified Answer
The correct answer is: 27cm of Hg
2 NH 3 g N 2 g + 3 H 2 7 6 - 2 x x 3 x

         7 6 + 2 x = 7 6 + 1 8

                  2 x = 1 8

∴               x = 9

∴           p H 2 = 3 × 9

                     =  27 cm of Hg

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