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Question: Answered & Verified by Expert
An organic compound is boiled with alcoholic potash. The product is cooled and acidified with HCl. A white solid separates out. The starting compound may be
ChemistryCarboxylic Acid DerivativesCOMEDKCOMEDK 2016
Options:
  • A ethyl acetate
  • B methyl acetate
  • C ethyl benzoate
  • D ethyl formate
Solution:
2163 Upvotes Verified Answer
The correct answer is: ethyl benzoate
Ethyl benzoate is boiled with alc. potash to give ethyl alcohol and potassium benzoate.



Potassium benzoate is converted into benzoic acid, a white solid which separates out.
$\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOK}+\mathrm{HCl} \rightarrow \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}+\mathrm{KCl}$

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