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Question: Answered & Verified by Expert
An unknown alcohol is treated with the Lucas reagent to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechansim?
ChemistryAlcohols Phenols and EthersJEE Main
Options:
  • A Tertiary alcohol by SN2
  • B Tertiary alcohol by SN1
  • C Secondary alcohol by SN2
  • D Secondary alcohol by SN1
Solution:
2031 Upvotes Verified Answer
The correct answer is: Tertiary alcohol by SN1
The reaction of alcohol with Lucas reagent is mostly an SN1 mechanism reaction and the rate of reaction is directly proportional to the carbocation stability formed in the reaction, hence tertiary alcohol will react fastest.

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