Aniline on treatment with conc. HNO 3 + conc. H 2 SO 4 mixture yields, o- and p-nitroanilines, m -nitroanilines, A black tarry matter, No reaction

Aniline on treatment with conc. HNO 3 + conc. H 2 SO 4 mixture yields

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Aniline on treatment with conc. $\mathrm{HNO}_3+$ conc. $\mathrm{H}_2 \mathrm{SO}_4$ mixture yields

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The correct answer is: A black tarry matter

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