Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
Arrange benzene, $n$-hexane and ethyne in decreasing order of their acidic behaviour.
ChemistryGeneral Organic ChemistryKCETKCET 2021
Options:
  • A Benzene $>n$-hexane $>$ Ethyne
  • B $n$-hexane $>$ Benzene $>$ Ethyne
  • C Ethyne $>n$-hexane $>$ Benzene
  • D Ethyne $>$ Benzene $>n$-hexane
Solution:
1295 Upvotes Verified Answer
The correct answer is: Ethyne $>$ Benzene $>n$-hexane
The decreasing order of acidic behaviour is ethyne $>$ benzene $>n$-hexane
Because carbon in ethyne, benzene and $n$-hexane are $s p, s p^{2}$ and $s p^{3}$ hybridised respectively.



$\therefore$ The carbocation formed after the removal of ' $\mathrm{H}$ ' is more stable in $s p$ hybridised carbon atom because of high electronegativity due to more $s$-character.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.