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Question: Answered & Verified by Expert
Arrange following carbocation in the decreasing order of stability
(i) CH3-C+H-CH3
(ii) CH3-C+H-O-CH3
(iii) CH3-C+H-CO-CH3
ChemistryGeneral Organic ChemistryNEET
Options:
  • A (iii)>(ii)>(i)
  • B (i)>(ii)>(iii)
  • C (ii)>(i)>(iii)
  • D (i)<(ii)<(iii)
Solution:
2421 Upvotes Verified Answer
The correct answer is: (ii)>(i)>(iii)
Carbocation are stabilised by back bonding and electron donating groups (EDG) while destabilised by electrons withdrawing groups (EWG).
CH3-C+H-O-CH3 (back bonding) > CH3-C+H-CH3 (EDG) > CH3-C+H-CO-CH3 (EWG)

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