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Arrange the following compounds in the correct order of their acid strength.

Options:

Solution:
2761 Upvotes
Verified Answer
The correct answer is:
$B>A>D>C$
Acidic strength of organic compounds can be determine on the basis of conjugate acid-base pairs.
$$
\mathrm{H}_2 \mathrm{O}+\mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{H}_3 \mathrm{O}^{+}+\mathrm{OH}^{-}
$$
Acid
Conjugate base

Conjugate base strength increase with increasing negative charge at oxygen.
$$
\text { Order of basic strength }
$$
Negative charge at oxygen atom increases due to electron releasing nature of methyl or ethyl group. Order of acid strength is inverse of basic strength.
$$
\text { Thus, option (4) is correct. }
$$
$$
\mathrm{H}_2 \mathrm{O}+\mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{H}_3 \mathrm{O}^{+}+\mathrm{OH}^{-}
$$
Acid
Conjugate base

Conjugate base strength increase with increasing negative charge at oxygen.
$$
\text { Order of basic strength }
$$

Negative charge at oxygen atom increases due to electron releasing nature of methyl or ethyl group. Order of acid strength is inverse of basic strength.

$$
\text { Thus, option (4) is correct. }
$$
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