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Question: Answered & Verified by Expert
Arrange the following in increasing order of their acidic strength
ChemistryGeneral Organic ChemistryAP EAMCETAP EAMCET 2022 (08 Jul Shift 1)
Options:
  • A $\mathrm{A} < \mathrm{C} < \mathrm{D} < \mathrm{B}$
  • B $\mathrm{A} < \mathrm{C} < \mathrm{B} < \mathrm{D}$
  • C $\mathrm{D} < \mathrm{C} < \mathrm{A} < \mathrm{B}$
  • D $\mathrm{A} < \mathrm{B} < \mathrm{C} < \mathrm{D}$
Solution:
1438 Upvotes Verified Answer
The correct answer is: $\mathrm{A} < \mathrm{B} < \mathrm{C} < \mathrm{D}$
More the stability of conjugate bases, more is the acidity of the acid. $\mathrm{Ph}, \mathrm{Br}, \mathrm{NO}_2$ exerts the $-\mathrm{I}$ effect to the $\mathrm{C}_{\propto}$ which, further, stabilizes the carboxylate ion.
Order of $(-\mathrm{I})$ effect of the substituents :
$\mathrm{H} < \mathrm{Ph} < \mathrm{Br} < \mathrm{NO}_2$

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