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Question: Answered & Verified by Expert
Arrange the following molecules according to decreasing order of their $\mathrm{O}-\mathrm{O}$ bond lengths.
ChemistryChemical Bonding and Molecular StructureAP EAMCETAP EAMCET 2021 (23 Aug Shift 2)
Options:
  • A $\mathrm{O}_3>\mathrm{H}_2 \mathrm{O}_2>\mathrm{O}_2$
  • B $\mathrm{H}_2 \mathrm{O}_2>\mathrm{O}_3>\mathrm{O}_2$
  • C $\mathrm{O}_2>\mathrm{H}_2 \mathrm{O}_2>\mathrm{O}_3$
  • D $\mathrm{O}_2>\mathrm{O}_3>\mathrm{H}_2 \mathrm{O}_2$
Solution:
2341 Upvotes Verified Answer
The correct answer is: $\mathrm{H}_2 \mathrm{O}_2>\mathrm{O}_3>\mathrm{O}_2$
$\mathrm{H}_2 \mathrm{O}_2$ has only single bond with bond length $1.41 Å$,
$\mathrm{O}_2$ has double bond with bond length $1.33 Å$.
$\mathrm{O}_3$ has a partial double bond due to resonance of lone pairs of electrons.


So, correct order is
$\mathrm{H}_2 \mathrm{O}_2>\mathrm{O}_3>\mathrm{O}_2$

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