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Question: Answered & Verified by Expert
Arrange the following organic halides in correct order of reactivity towards \(\mathrm{S}_{\mathrm{N}} 2\) displacement.

ChemistryHaloalkanes and HaloarenesAP EAMCETAP EAMCET 2019 (20 Apr Shift 1)
Options:
  • A \(P > Q > R\)
  • B \(R > P > Q\)
  • C \(P > R > Q\)
  • D \(Q > R > P\)
Solution:
1085 Upvotes Verified Answer
The correct answer is: \(Q > R > P\)


\(3^{\circ}\) alkyl halide (highly sterically hindered)

\(1^{\circ}\) alkyl halide (least sterically hindered)

(R) \(2^{\circ}\) alkyl halide
Rate of \(\mathrm{S}_{\mathrm{N}} 2\) reaction \(\propto \frac{1}{\text { sterically hindrance }}\)
\(\therefore\) Rate is \(1^{\circ} > 2^{\circ} > 3^{\circ}\) alkyl halide.
Hence, \(Q > R > P\) is correct answer.

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